Synthesis, Electrochemistry and Spectroscopic Properties of Ruthenium Phthalocyanine and Naphthalocyanine Complexes with Triphenylarsine Ligands

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dc.contributor.author Rawling, Tristan en_US
dc.contributor.author Mcdonagh, Andrew en_US
dc.contributor.author Colbran, Stephen en_US
dc.contributor.editor en_US
dc.date.accessioned 2010-05-28T09:43:25Z
dc.date.available 2010-05-28T09:43:25Z
dc.date.issued 2008 en_US
dc.identifier 2008000034 en_US
dc.identifier.citation Rawling Tristan, Mcdonagh Andrew, and Colbran Stephen 2008, 'Synthesis, Electrochemistry and Spectroscopic Properties of Ruthenium Phthalocyanine and Naphthalocyanine Complexes with Triphenylarsine Ligands', Elsevier, vol. 361, pp. 49-55. en_US
dc.identifier.issn 0020-1693 en_US
dc.identifier.other C1 en_US
dc.identifier.uri http://hdl.handle.net/10453/8473
dc.description.abstract The synthesis, electrochemistry and spectroscopic properties of [PcRu(AsPh3)2] (1) and [{(tBu)4Nc}Ru(AsPh3)2] (2), where Pc = phthalocyanine and Nc = naphthalocyanine are reported. These complexes are the first examples of metal phthalocyanine and naphthalocyanine complexes with axially-coordinated arsine ligands. The AsPh3 ligands readily dissociate in non-coordinating solvents with 2 showing more rapid dissociation. In cyclic voltammetry experiments, 1 displayed three macrocycle-centred redox processes; one reduction and two oxidation processes. One reduction and three oxidation processes were observed for 2. The reduction and first oxidation are assigned to macrocycle-centred processes. The UV?Vis spectra of both complexes recorded over time showed macrocycle-centred oxidation. The oxidation was hindered by removing dioxygen from the solvent or adding excess AsPh3. en_US
dc.language en_US
dc.publisher Elsevier en_US
dc.relation.hasversion Accepted manuscript version en_US
dc.relation.isbasedon http://dx.doi.org/10.1016/j.ica.2007.06.043 en_US
dc.rights NOTICE: this is the author’s version of a work that was accepted for publication in Inorganica Chimica Acta. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Inorganica Chimica Acta Volume 361, Issue 1, 1 January 2008, Pages 49–55 DOI#”http://dx.doi.org/10.1016/j.ica.2007.06.043 en_US
dc.title Synthesis, Electrochemistry and Spectroscopic Properties of Ruthenium Phthalocyanine and Naphthalocyanine Complexes with Triphenylarsine Ligands en_US
dc.parent Inorganic Chimica Acta en_US
dc.journal.volume 361 en_US
dc.journal.number en_US
dc.publocation Amsterdam en_US
dc.identifier.startpage 49 en_US
dc.identifier.endpage 55 en_US
dc.cauo.name SCI.Faculty of Science en_US
dc.conference Verified OK en_US
dc.for 030200 en_US
dc.personcode 040731 en_US
dc.personcode 030871 en_US
dc.personcode 0000024606 en_US
dc.percentage 100 en_US
dc.classification.name Inorganic Chemistry en_US
dc.classification.type FOR-08 en_US
dc.edition en_US
dc.custom en_US
dc.date.activity en_US
dc.location.activity ISI:000253226700008 en_US
dc.description.keywords Ruthenium; Phthalocyanine; Naphthalocyanine; Arsine; Electrochemistry en_US


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