Structure and Properties of Redox Active Self-Assembled Monolayers Formed from Norbornylogous Bridges

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dc.contributor.author Eggers, Pk en_US
dc.contributor.author Zareie, Hadi en_US
dc.contributor.author Paddon-Row, Michael en_US
dc.contributor.author Gooding, John en_US
dc.contributor.editor en_US
dc.date.accessioned 2010-05-28T09:43:14Z
dc.date.available 2010-05-28T09:43:14Z
dc.date.issued 2009 en_US
dc.identifier 2008007775 en_US
dc.identifier.citation Eggers Pk et al. 2009, 'Structure and Properties of Redox Active Self-Assembled Monolayers Formed from Norbornylogous Bridges', Amer Chemical Soc, vol. 25, no. 18, pp. 11090-11096. en_US
dc.identifier.issn 0743-7463 en_US
dc.identifier.other C1 en_US
dc.identifier.uri http://hdl.handle.net/10453/8439
dc.description.abstract Three different length rigid norbornylogous bridges with terminal ferrocene moieties were synthesized. Pure self-assembled monolayers (SAMs) of the norbornylogous bridges and SAMs with the bridges diluted using either hydroxyl-terminated or methyl-terminated diluents were formed for each length of norbornylogous bridge. The SAMs were imaged with scanning tunneling micrsocopy (STM) and the electrochemical properties were Investigated. It was found that SAMs composed of only norbornylogous bridges were crystalline-like, while in mixed SAMs, where the norbornylogous bridge was diluted, the ferrocene stood above the surface of the diluent because of the rigidity of the norbornylogous bridges and were homogeneously distributed across the surface. Further. the rate of electron transfer of the norbornylogous bridges was observed to be similar to an alkanethiol-derived ferrocene whose construct was designed to be as close as possible to that of the norbornylogous bridge. Finally, the rate of electron transfer for the norbornylogous bridges in a diluted SAM was slower With it hydroxyl-terminated diluent. than with a methyl-terminated diluent. en_US
dc.language en_US
dc.publisher Amer Chemical Soc en_US
dc.relation.isbasedon http://dx.doi.org/10.1021/la9012558 en_US
dc.title Structure and Properties of Redox Active Self-Assembled Monolayers Formed from Norbornylogous Bridges en_US
dc.parent Langmuir en_US
dc.journal.volume 25 en_US
dc.journal.number 18 en_US
dc.publocation Washington, USA en_US
dc.identifier.startpage 11090 en_US
dc.identifier.endpage 11096 en_US
dc.cauo.name SCI.Faculty of Science en_US
dc.conference Verified OK en_US
dc.for 030600 en_US
dc.personcode 0000052808 en_US
dc.personcode 030414 en_US
dc.personcode 0000017445 en_US
dc.personcode X000017042 en_US
dc.percentage 100 en_US
dc.classification.name Physical Chemistry (incl. Structural en_US
dc.classification.type FOR-08 en_US
dc.edition en_US
dc.custom en_US
dc.date.activity en_US
dc.location.activity ISI:000269655000093 en_US
dc.description.keywords NA en_US


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