Manganese-based layered coordination polymer: Synthesis, structural characterization, magnetic property, and electrochemical performance in lithium-ion batteries

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dc.contributor.author Horvat, Josip en_US
dc.contributor.author Liu, Qi en_US
dc.contributor.author Yu, Lili en_US
dc.contributor.author Ji, Yunzhou en_US
dc.contributor.author Cheng, Mei-Ling en_US
dc.contributor.author Jia, Xiaoyan en_US
dc.contributor.author Wang, Guoxiu en_US
dc.contributor.author Wang, Ying en_US
dc.contributor.editor en_US
dc.date.accessioned 2013-11-03T17:05:35Z
dc.date.available 2013-11-03T17:05:35Z
dc.date.issued 2013 en_US
dc.identifier 2012001629 en_US
dc.identifier.citation Horvat, Josip et al. 2013, 'Manganese-based layered coordination polymer: Synthesis, structural characterization, magnetic property, and electrochemical performance in lithium-ion batteries', American Chemical Society, vol. 52, pp. 2817-2882. en_US
dc.identifier.issn 0020-1669 en_US
dc.identifier.other C1 en_US
dc.identifier.uri http://hdl.handle.net/10453/24050
dc.description.abstract Manganese-based layered coordination polymer ([Mn- (tfbdc)(4,4!-bpy)(H2O)2], Mn-LCP) with microporous structure was synthesized by reaction of 2,3,5,6-tetrafluoroterephthalatic acid(H2tfbdc) and 4,4!-bipyridine(4,4!-bpy) with manganese(II) acetate tetrahydrate in water solution. Mn-LCP was characterized by elemental analysis, IR spectra, thermogravimetric analysis, X-ray single-crystal structure analysis, and powder X-ray diffraction. Magnetic susceptibility data from 300 to 1.8K show that there is a weak antiferromagnetic exchange between Mn(II) ions in Mn-LCP. As anode material, the Mn-LCP electrode exhibits an irreversible high capacity in the first discharge process and a reversible lithium storage capacity of up to about 390 mA h/g from the fourth cycle. It might provide a new method for finding new electrode materials in lithium-ion batteries en_US
dc.language en_US
dc.publisher American Chemical Society en_US
dc.relation.isbasedon en_US
dc.title Manganese-based layered coordination polymer: Synthesis, structural characterization, magnetic property, and electrochemical performance in lithium-ion batteries en_US
dc.parent Inorganic Chemistry en_US
dc.journal.volume 52 en_US
dc.journal.number en_US
dc.publocation United States en_US
dc.identifier.startpage 2817 en_US
dc.identifier.endpage 2882 en_US
dc.cauo.name SCI.School of Chemistry and Forensic Science SCI.School of Chemistry and Forensic Science SCI.School of Chemistry and Forensic Science en_US
dc.conference Verified OK en_US
dc.for 091200 en_US
dc.personcode 0000027091 en_US
dc.personcode 0000077025 en_US
dc.personcode 0000091445 en_US
dc.personcode 0000091446 en_US
dc.personcode 0000091447 en_US
dc.personcode 0000091449 en_US
dc.personcode 109499 en_US
dc.personcode 112017 en_US
dc.percentage 50 en_US
dc.classification.name Materials Engineering en_US
dc.classification.type FOR-08 en_US
dc.edition en_US
dc.custom en_US
dc.date.activity en_US
dc.location.activity en_US
dc.description.keywords en_US
dc.staffid 112017 en_US


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