Chemical Analysis Of The Superatom Model For Sulfur-Stabilized Gold Nanoparticles

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Chemical Analysis Of The Superatom Model For Sulfur-Stabilized Gold Nanoparticles

Reimers Jr; Wang Yiyan; Cankurtaran Burak; Ford Matthew
URI: http://hdl.handle.net/10453/13139
Date: 2010

Abstract:

The superatom model for nanoparticle structure is shown to be inadequate for the prediction of the thermodynamic stability of gold nanoparticles. The observed large HOMO-LUMO gaps for stable nanoparticles predicted by this model are, for sulfur-stabilize

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