Synthesis and characterization of SrBi4Ti4O15 ferroelectric filler based composite polymer electrolytes for lithium ion batteries

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dc.contributor.author Shanmukaraj, Devaraj en_US
dc.contributor.author Wang, Guoxiu en_US
dc.contributor.author Liu, H. en_US
dc.contributor.author Murugan, R. en_US
dc.contributor.editor en_US
dc.date.accessioned 2011-02-07T06:18:48Z
dc.date.available 2011-02-07T06:18:48Z
dc.date.issued 2008 en_US
dc.identifier 2009006613 en_US
dc.identifier.citation Shanmukaraj D. et al. 2008, 'Synthesis and characterization of SrBi4Ti4O15 ferroelectric filler based composite polymer electrolytes for lithium ion batteries', Springer Berlin, vol. 60, no. NA, pp. 351-361. en_US
dc.identifier.issn 0170-0839 en_US
dc.identifier.other C1UNSUBMIT en_US
dc.identifier.uri http://hdl.handle.net/10453/13100
dc.description.abstract Composite polymer electrolytes (CPEs) based on poly (ethylene oxide) (PEO) (Mol.Wt ~ 6 x 105) complexed with LiN(CF3SO2)2 lithium salt and SrBi4Ti4O15 ferroelectric ceramic filler have been prepared as films. Citrate gel technique and conventional solid state technique were employed for the synthesis of the ferroelectric fillers in order to study the effect of particle size of the filler on ionic conductivity of the polymer electrolyte. Characterization techniques such as X-ray diffraction (XRD), differential thermal analysis (DTA), scanning electron microscopy (SEM) and temperature dependant DC conductivity studies were taken for the prepared polymer composite electrolytes. The broadening of DTA endotherms on addition of ceramic fillers to the polymer salt complex indicated the reduction in crystallinity. An enhancement in conductivity was observed with the addition of SrBi4Ti4O15 as filler to the (PEO)8-LiN(CF3SO2)2 polymer salt complexes. Among the investigated samples (PEO)8-LiN(CF3SO2)2 +10 wt% SrBi4Ti4O15 (citrate gel) polymer composite exhibits a maximum conductivity. en_US
dc.language en_US
dc.publisher Springer Berlin en_US
dc.relation.isbasedon http://dx.doi.org/10.1007/s00289-007-0845-y en_US
dc.title Synthesis and characterization of SrBi4Ti4O15 ferroelectric filler based composite polymer electrolytes for lithium ion batteries en_US
dc.parent Polymer Bulletin en_US
dc.journal.volume 60 en_US
dc.publocation Heidelberg en_US
dc.identifier.startpage 351 en_US
dc.identifier.endpage 361 en_US
dc.cauo.name SCI.Faculty of Science en_US
dc.conference Verified OK en_US
dc.for 030300 en_US
dc.personcode 0000062969 en_US
dc.personcode 109499 en_US
dc.personcode 0000062748 en_US
dc.personcode 0000062970 en_US
dc.percentage 100 en_US
dc.classification.name Macromolecular and Materials Chemistry en_US
dc.classification.type FOR-08 en_US
dc.edition en_US
dc.custom en_US
dc.date.activity en_US
dc.location.activity en_US
dc.description.keywords NA en_US
dc.staffid en_US


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